Tungstate sulfuric acid (TSA)/KMnO4 as a novel heterogeneous system for rapid deoximation.
نویسندگان
چکیده
Neat chlorosulfonic acid reacts with anhydrous sodium tungstate to give tungstate sulfuric acid (TSA), a new dibasic inorganic solid acid in which two sulfuric acid molecules connect to a tungstate moiety via a covalent bond. A variety of oximes were oxidized to their parent carbonyl compounds under mild conditions with excellent yields in short times by a heterogeneous wet TSA/KMnO4 in dichloromethane system.
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ورودعنوان ژورنال:
- Molecules
دوره 11 9 شماره
صفحات -
تاریخ انتشار 2006